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篇目详细内容 |
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【篇名】 |
Photo-induced electron transfer study of rhenium(I) bipyridyl complexes with covalently linked phenothiazine donor through different bridge |
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【刊名】 |
Frontiers of Chemistry in China |
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【刊名缩写】 |
Front. Chem. China |
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【ISSN】 |
1673-3495 |
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【EISSN】 |
1673-3614 |
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【DOI】 |
10.1007/s11458-010-0111-y |
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【出版社】 |
Higher Education Press and Springer-Verlag Berlin
Heidelberg |
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【出版年】 |
2010 |
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【卷期】 |
5
卷2期 |
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【页码】 |
171-177
页,共
7
页 |
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【作者】 |
Shiguo SUN;
Lei SHI;
Fengyu LIU;
Jiangli FAN;
Xiaojun PENG;
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【关键词】 |
rhenium(I) bipyridyl complex; intermolecular electron transfer; intramolecular electron transfer; phenothiazine; acceptor |
【摘要】 |
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A novel rhenium(I) bipyridyl complex 1a, [(4,4’-di-COOEt-bpy)Re(CO)3(py-NHCO-PTZ)PF6] and a model 1b, [(4,4’-di-COOEt-bpy)Re(CO)3(py-PTZ)PF6] (bpy is 2, 2’-bipyridine, py-NHCO-PTZ is phenothiazine-(10-carbonyl amide) pyridine and py-PTZ is 10-(4-picolyl) phenothiazine) were synthesized. Their photo-induced electron transfer (ET) reaction with electron acceptor methyl viologen (MV2+) in acetonitrile was studied by nanosecond laser flash photolysis at room temperature. Photoexcitation of 1 in the presence of MV2+ led to ET from the Re moiety to MV2+ generating Re(II) and methyl viologen radical (MV．+). Then Re(II) was reduced either by the charge recombination with MV．+ or by intramolecular ET from the attached PTZ, regenerating the photosensitizer Re(I) and forming the PTZ radical at 510 nm. In the case of 1b, the absorption for PTZ radical can be observed distinctly accompanied intermolecular ET, whereas not much difference at 510 nm can be detected for 1a on the time scale of the experiments. This demonstrates that the linking bridge plays a key role on the intramolecular ET in complex 1. |
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