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篇目详细内容 |
【篇名】 |
Goethite-enhanced anaerobic bio-decomposition of sulfate minerals |
【刊名】 |
Frontiers of Earth Science in China |
【刊名缩写】 |
Front. Earth Sci. China |
【ISSN】 |
1673-7385 |
【EISSN】 |
1673-7490 |
【DOI】 |
10.1007/s11707-010-0020-x |
【出版社】 |
Higher Education Press and Springer-Verlag Berlin
Heidelberg |
【出版年】 |
2010 |
【卷期】 |
4
卷2期 |
【页码】 |
160-166
页,共
7
页 |
【作者】 |
Tianhu CHEN;
Jin WANG;
Xin JIN;
Zhengbo YUE;
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【关键词】 |
goethite; sulfate-reducing bacteria; sulfate minerals; gypsum; anhydrite |
【摘要】 |
The effects of goethite on the anaerobic bio-decomposition of sulfate minerals were investigated by using the beef extract as a carbon source and the activated sludge as the source of mixed bacteria. Solution pH, sulfate concentration, total iron ion concentration and the solid products of four different batch tests were monitored and analyzed. Experimental results showed that the presence of iron oxide can improve the alkalinity of the reaction system which results in the increase of pH value. Moreover, the added goethite consumed a large amount of H2S generated from the sulfate minerals by SRB, thereby significantly enhancing the decomposition of gypsum and anhydrite compared with the control batch tests. In addition, the SEM observation and the EDS spectra showed that there were some rod-shaped microorganisms and new generated minerals, such as iron sulfide, calcium carbonate crystals, and elemental sulfur. Both of the proliferation of new minerals (iron sulfide and calcium carbonate crystals) and the complete disappearance of sulfate minerals indicated that iron oxide can play the role in fixing the S element through the metabolism of SRB and hence improve the bio-decomposition of sulfate minerals. |
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