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篇目详细内容 |
【篇名】 |
Semiclassical treatments of electron transfer rate from weak to strong electronic coupling regime |
【刊名】 |
Frontiers of Chemistry in China |
【刊名缩写】 |
Front. Chem. China |
【ISSN】 |
1673-3495 |
【EISSN】 |
1673-3614 |
【DOI】 |
10.1007/s11458-010-0219-0 |
【出版社】 |
Higher Education Press and Springer-Verlag Berlin
Heidelberg |
【出版年】 |
2010 |
【卷期】 |
5
卷4期 |
【页码】 |
423-434
页,共
12
页 |
【作者】 |
Yi ZHAO;
Wanzhen LIANG;
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【关键词】 |
electron transfer (ET); solvent dynamic effect; electronic coupling; theoretical study |
【摘要】 |
Electron transfer (ET) rate is a fundamental parameter to characterize ET processes in physical, chemical, material and biologic sciences. It is affected by a number of quantum phenomena, such as nuclear tunneling, curve crossing, quantum interference, and the coupling to the environment. It is thus a challenge to accurately evaluate the ET rate since one has to incorporate both quantum effects and dissipation. In this review article, we present several semiclassical theories proposed in our group to cover the regime from weak to strong electronic coupling. Their applications to some concrete systems are also shown. |
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