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篇目详细内容

【篇名】 Intermediate structures in two-dimensional molecular self-assembly
【刊名】 Frontiers of Physics in China
【刊名缩写】 Front. Phys. China
【ISSN】 1673-3487
【EISSN】 1673-3606
【DOI】 10.1007/s11467-010-0106-7
【出版社】 Higher Education Press and Springer-Verlag Berlin Heidelberg
【出版年】 2010
【卷期】 5 卷4期
【页码】 340-346 页,共 7 页
【作者】 Karl-Heinz ERNST;
【关键词】 scanning tunnelling microscopy (STM); polymorphism; corannulene; heptahelicene; chirality

【摘要】
We discuss the occurrence of transition structures observed in molecular self-assembly at surfaces. The increasing surface coverage transitions from low coverage structures to high coverage structures are a common phenomenon. However, often observed and not perfectly understood is the formation of intermediate structures, sometimes with lower lateral density than the initial phase. We will present different examples from our recent work and discuss the possible mechanisms of intermediate phase formation. In addition, we present intermediate structures occurring due to temperature-controlled reversible phase transitions.
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