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篇目详细内容 |
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【篇名】 |
Dependence of porosity, charge recombination kinetics and photovoltaic performance on annealing condition of TiO2 films |
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【刊名】 |
Frontiers of Optoelectronics in China |
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【刊名缩写】 |
Front. Optoelectron. China |
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【ISSN】 |
1674-4128 |
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【EISSN】 |
1674-4594 |
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【DOI】 |
10.1007/s12200-011-0205-2 |
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【出版社】 |
Higher Education Press and Springer-Verlag Berlin
Heidelberg |
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【出版年】 |
2011 |
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【卷期】 |
4
卷1期 |
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【页码】 |
59-64
页,共
6
页 |
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【作者】 |
Chang-Ryul LEE;
Hui-Seon KIM;
Nam-Gyu PARK;
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【关键词】 |
dye-sensitized solar cell (DSSC); annealing conditions; surface area; porosity; electron life time |
【摘要】 |
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Effect of annealing temperature, time of nanocrystalline TiO2 film on porosity, electron transport/recombination and photovoltaic performance on dye-sensitized solar cell (DSSC) had been investigated in this article. Photocurrent density was slightly higher as annealing at 550°C compared to those of annealing at 450°C and 500°C under the given annealing time of 60？min, which was correlated with the amount of adsorbed dye. Thermogravimetric analysis showed there was a more weight loss between 500°C and 550°C, which revealed there were more sites for dye adsorption. Given the annealing temperature of 550°C, as annealing time varied from 60 to 90 and 120？min, results showed that the average size of pore and surface area decreased with longer annealing time, which deteriorated photocurrent density due to less dye loading. Electron diffusion rate remained almost unchanged regardless of annealing condition. However, electron recombination was influenced by annealing condition, it became slower with the increase of the annealing temperature under the given annealing time. In the contray, the electron recombination developed faster for the longer annealing time at a given annealing temperature. These results suggested that heat treatment of TiO2 film at 550°C for 60？min in air would be the optimal annealing condition to achieve high efficiency DSSC. |
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