Well-aligned ZnO nanorod arrays were prepared on FTO substrate by hydrothermal method at low temperature for 5?h. The effect of ammonia on the length of ZnO nanorod was studied in detail. The resulting materials were extensively characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and UV-visible absorption spectra (scatter mode). With the increase of ammonia, the length of ZnO nanorod increases.