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篇目详细内容 |
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【篇名】 |
Synthesis and crystal structure of inclusion compounds: Trans-9,10-dihydro-9,10-ethanoanthracene-11,12-dicarboxylic acid with boric acid and tetrabutylammonium salt |
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【刊名】 |
Frontiers of Chemistry in China |
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【刊名缩写】 |
Front. Chem. China |
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【ISSN】 |
1673-3495 |
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【EISSN】 |
1673-3614 |
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【DOI】 |
10.1007/s11458-007-0054-0 |
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【出版社】 |
Higher Education Press and Springer-Verlag |
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【出版年】 |
2007 |
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【卷期】 |
2
卷3期 |
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【页码】 |
296-302
页,共
7
页 |
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【作者】 |
YANG Yuan;
ZHANG Jinnan;
LUO Surong;
SONG Xiaohong;
LI Qi;
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【关键词】 |
Trans-9;10-dihydro-9;10-ethanoanthracene-11;12-dicarboxylic acid; boric acid; tetra-n-butylammonium salt; inclusion compound; crystal structure |
【摘要】 |
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Two new inclusion compounds (n-C4H9)4N+C18H13O4? · B(OH)3 (1) and (n-C4H9)4N+C18H13O4? (2) were prepared and characterized by X-ray crystallography. Crystal data: compound 1, monoclinic P2(1)/c, a = 1.569 9(1) nm, b = 0.995 5(6) nm, c = 2.293 3(1) nm, β = 109.962(3)°, Z = 4, and R1 = 0.0434, wR = 0.075 9; compound 2, monoclinic C2/c, a = 1.400 5(3) nm, b = 1.282 1(2) nm, c = 1.765 7(3) nm, β = 100.388(1)°, Z = 4, and R1 = 0.0584, wR = 0.096 6. In the crystal structure of 1, the tetramers formed by two trans-9,10-dihydro-9,10-ethanoanthracene-11,12-dicarboxylic acid (EADA) anions and two boric acid molecules were connected through O—H···O hydrogen bonds to generate a channel type host lattice. The tetra-n-butylammonium cations were stacked to give two columns within each channel with cross-sectional size of about 2.30 nm×0.93 nm. In the crystal structure of 2, similar honeycomb host lattices with big size were also formed along the [101] direction by three-dimensional accumulation of EADA anions. The tetra-n-butylammonium cations were accommodated in a zigzag fashion within each channel. |
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