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篇目详细内容 |
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【篇名】 |
Modeling of ion conductivity in Nafion membranes |
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【刊名】 |
Frontiers of Energy and Power Engineering in China |
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【刊名缩写】 |
Front. Energy Power Eng. China |
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【ISSN】 |
1673-7393 |
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【EISSN】 |
1673-7504 |
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【DOI】 |
10.1007/s11708-007-0005-y |
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【出版社】 |
Higher Education Press and Springer-Verlag |
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【出版年】 |
2007 |
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【卷期】 |
1
卷1期 |
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【页码】 |
58-66
页,共
9
页 |
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【作者】 |
YANG Zhen;
PENG Xiaofeng;
WANG Buxuan;
LEE Duujong;
DUAN Yuanyuan;
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【关键词】 |
cluster; the equivalent field; ionic conductivity; surface energy |
【摘要】 |
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A theoretical investigation was conducted to describe the ion transport behavior in a Nafion Membrane of proton exchange membrane fuel cells (PEMFC). By analyzing the surface energy configuration of the ionic clusters in a Nafion membrane, an equivalent field intensity, Ee, was introduced to facilitate the analysis of surface resistance against ion conduction in the central region of clusters. An expression was derived for ionic conductivity incorporating the influence of surface resistance. A face-centered cubic (FCC) lattice model for a spatial cluster distribution was used to modify the effect of water content on ionic conductivity in the polymeric matrix, i.e., the regions between clusters. Compared with the available empirical correlations, the new expression showed much better agreement with the available experimental results, which indicates the rationality to consider the structural influence on ion conduction in water-swollen Nafion membranes. |
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