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篇目详细内容

【篇名】 Transition metal doped mesoporous titania with a crystalline framework as catalysts for oxidation of p-bromotoluene to p-bromobenzaldehyde
【刊名】 Frontiers of Chemical Engineering in China
【刊名缩写】 Front. Chem. Eng. China
【ISSN】 1673-7369
【EISSN】 1673-7474
【DOI】 10.1007/s11705-008-0044-x
【出版社】 Higher Education Press and Springer-Verlag
【出版年】 2008
【卷期】 2 卷3期
【页码】 296-300 页,共 5 页
【作者】 YANG Zehui; YIN Lihui; OU Encai; WANG Yunan; PENG Li; WANG Jiaqiang;
【关键词】 Oxidation; p-Bromotoluene; p-Bromobenzaldehyde; Crystalline cobalt; mesoporous titania

【摘要】
Transition metal M (M = Mn, Fe, Co, Ni, Cu, and Zn) doped mesoporous titania with a crystalline framework was employed as catalysts for the oxidation of p-bromotoluene (PBT) to p-bromobenzaldehyde (BBD) in acetic acid using aqueous hydrogen peroxide as oxidant. It was found that mesoporous TiO2 doped with those metals (Fe, Co and Ni) whose atomic radii are relatively smaller exhibited higher conversion rate of PBT. Among these catalysts, the Co/meso-TiO2 exhibited high substrate conversion and good product (p-bromobenzaldehyde) selectivity plus it can be reused once with almost the same activity. The effect of different Ti/Co (molar) ratio on the activities of Co/meso-TiO2 was also investigated.
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