|
|
|
篇目详细内容 |
|
【篇名】 |
Modeling of specific structure crystallization coupling with dissolution |
|
【刊名】 |
Frontiers of Chemical Engineering in China |
|
【刊名缩写】 |
Front. Chem. Eng. China |
|
【ISSN】 |
1673-7369 |
|
【EISSN】 |
1673-7474 |
|
【DOI】 |
10.1007/s11705-009-0301-7 |
|
【出版社】 |
Higher Education Press and Springer-Verlag Berlin
Heidelberg |
|
【出版年】 |
2010 |
|
【卷期】 |
4
卷1期 |
|
【页码】 |
52-56
页,共
5
页 |
|
【作者】 |
Yuanhui JI;
Hongliang QIAN;
Chang LIU;
Xiaoyan JI;
Xiaohua LU;
Xin FENG;
|
|
【关键词】 |
activity coefficient model; solid-liquid equilibrium; dissolution kinetics; crystallization modeling; porous structures; microphase separation |
【摘要】 |
|
In this paper, the research framework for specific structure crystallization modeling has been proposed in which four steps are required in order to investigate the rigorous crystallization modeling by thermodynamics. The first is the activity coefficient model of the solution, the second is Solid-Liquid equilibrium, the third and fourth are the dissolution and crystallization kinetics modeling, respectively. Our investigations show that the mechanisms of complex structure formation and microphase transition can be analyzed by combining the dissolution and crystallization kinetics modeling. Moreover, the formation mechanism of the porous KCl has been analyzed, which may provide a reference for the porous structure formation in the advanced material synthesis. |
|
