|
|
|
篇目详细内容 |
|
【篇名】 |
The catalytic effect of both oxygen-bearing functional group and ash in carbonaceous catalyst on CH4-CO2 reforming |
|
【刊名】 |
Frontiers of Chemical Engineering in China |
|
【刊名缩写】 |
Front. Chem. Eng. China |
|
【ISSN】 |
1673-7369 |
|
【EISSN】 |
1673-7474 |
|
【DOI】 |
10.1007/s11705-009-0242-1 |
|
【出版社】 |
Higher Education Press and Springer-Verlag |
|
【出版年】 |
2010 |
|
【卷期】 |
4
卷2期 |
|
【页码】 |
147-152
页,共
6
页 |
|
【作者】 |
Weidong ZHANG;
Yongfa ZHANG;
|
|
【关键词】 |
carbonaceous catalyst; CH4-CO2 reforming; oxygen-bearing functional group; ash |
【摘要】 |
|
A kind of new catalyst—carbonaceous catalyst—for CH4-CO2 reformation has been developed in our laboratory. The effect of both oxygen-bearing functional group such as phenolic hydroxyl, carbonyl, carboxyl, and lactonic, and ash such as Fe2O3, Na2CO3, and K2CO3 in the carbonaceous catalyst on the CH4-CO2 reforming has been investigated with a fixed-bed reactor. It has been found that the carbonaceous catalyst is an efficient catalyst on CO2-CH4 reforming. With the decrease of oxygen-bearing functional group, the catalytic activity of carbonaceous catalyst decreases quickly. The oxygen-bearing functional groups play a significant role in the carbonaceous-catalyzed CO2-CH4 reforming; the ash components in carbonaceous catalyst also have an important influence on the CO2-CH4 reforming. Fe2O3, Na2CO3, and K2CO3 in the ash can catalyze the CO2-CH4 reforming reaction; CaO has little effect on CO2-CH4 reforming reaction. CaO can catalyze the gasification between carbonaceous catalyst and CO2; Al2O3 and MgO inhibit the CO2-CH4 reforming. |
|
