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篇目详细内容 |
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【篇名】 |
Synthesis of ultrafine ZrB2 powders by sol-gel process |
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【刊名】 |
Frontiers of Materials Science in China |
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【刊名缩写】 |
Front. Mater. Sci. China |
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【ISSN】 |
1673-7377 |
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【EISSN】 |
1673-7482 |
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【DOI】 |
10.1007/s11706-010-0094-0 |
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【出版社】 |
Higher Education Press and Springer-Verlag Berlin
Heidelberg |
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【出版年】 |
2010 |
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【卷期】 |
4
卷3期 |
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【页码】 |
285-290
页,共
6
页 |
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【作者】 |
Li-Juan YANG;
Shi-Zhen ZHU;
Qiang XU;
Zhen-Yu YAN;
Ling LIU;
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【关键词】 |
ultrafine ZrB2 powders; sol-gel method; synthesis |
【摘要】 |
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Ultrafine zirconium diboride (ZrB2) powders have been synthesized by sol-gel process using zirconium oxychloride (ZrOCl2·8H2O), boric acid (H3BO3) and phenolic resin as sources of zirconia, boron oxide and carbon, respectively. The effects of the reaction temperature, B/Zr ratio, holding time, and EtOH/H2O ratio on properties of the synthesized ZrB2 powders were investigated. It was revealed that ultrafine (average crystallite size between 100 and 400？nm) ZrB2 powders can be synthesized with the optimum processing parameters as follows: (i) the ratio of B/Zr is 4; (ii) the solvent is pure ethanol; (iii) the condition of carbothermal reduction heat treatment is at 1550°C for 20？min. |
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