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篇目详细内容 |
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【篇名】 |
Preparation and characterization of carbosilane dendrimer-bonded silica gel and its use in LC |
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【刊名】 |
Frontiers of Chemistry in China |
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【刊名缩写】 |
Front. Chem. China |
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【ISSN】 |
1673-3495 |
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【EISSN】 |
1673-3614 |
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【DOI】 |
10.1007/s11458-006-0036-7 |
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【出版社】 |
Higher Education Press and Springer-Verlag |
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【出版年】 |
2006 |
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【卷期】 |
1
卷3期 |
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【页码】 |
324-328
页,共
5
页 |
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【作者】 |
Chen Guowen;
Zhao Shigui;
Feng Shengyu;
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【关键词】 |
carbosilane dendrimer; chemically modified silica-based stationary phases; new type of reversed phase; LC |
【摘要】 |
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Divergently synthesized carbosilane dendrimers generations 1 (G1) and 2 (G2) with allyl end groups were bonded onto silica gel. Reactions between the dendrimers and acid-processed silica gel took place, with toluene reflux and organic base as catalyst. Chemically bonded silica gel was characterized by transmission electron microscopy (TEM), infrared (IR)，and other methods. The chemically modified silica gels were packed into high-pressure liquid chromatography (HPLC) column and their separation characters were evaluated. G2-bonded silica gel was effective in separating homologous compounds of alcohol, alkyl-substituted benzene, N-substituted benzene, metacrylic acid ester and phthalate. |
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