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篇目详细内容 |
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【篇名】 |
Effect of K and Ca on catalytic activity of Mn-CeOx/Ti-PILC |
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【刊名】 |
Frontiers of Environmental Science and Engineering in China |
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【刊名缩写】 |
Front.Environ.Sci.Engin.China |
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【ISSN】 |
2095-2201 |
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【EISSN】 |
2095-221X |
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【DOI】 |
10.1007/s11783-013-0519-y |
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【出版社】 |
Higher Education Press and Springer-Verlag Berlin
Heidelberg |
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【出版年】 |
2013 |
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【卷期】 |
7
卷4期 |
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【页码】 |
512-517
页,共
6
页 |
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【作者】 |
Boxiong SHEN;
Lidan DENG;
Jianhong CHEN;
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【关键词】 |
Mn-CeOx/Ti-pillared clay (PILC); low-temperature selective catalytic reduction (SCR); K and Ca poisoning effect |
【摘要】 |
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Mn-CeOx/Ti-pillared clay (PILC) is an attractive catalyst for selective catalytic reduction of NOx at low temperature because of its low cost. The poisoning of K and Ca on the catalyst of Mn-CeOx/Ti-PILC is an important problem because K and Ca are always in presence in flue gas. To investigate the effect of K and Ca on the physicochemical characters of the catalysts, the techniques of NH3-temperature programmed desorption (TPD), H2-temperature programmed reduction (TPR), and X-ray photoelectron spectroscopy (XPS) were used to analyze the fresh and deactivated catalysts of Mn-CeOx/Ti-PILC. (Ca)Mn-CeOx/Ti-PILC and (K)Mn-CeOx/Ti-PILC are denoted for the dopes of the catalyst of Mn-CeOx/Ti-PILC with Ca and K, respectively. The activities of Mn-CeOx/Ti-PILC, (Ca)Mn-CeOx/Ti-PILC and (K)Mn-CeOx/Ti-PILC for NH3-selective catalytic reduction (SCR) reaction at low temperature were investigated. The results showed that with the dopes of K and Ca on the catalysts, the SCR activities of the catalysts decreased greatly, and K exhibited more poisoning effect than Ca. With the dopes of K and Ca, the acidity, the redox property and chemisorbed oxygen on the surfaces of the catalysts were decreased, which resulted in a decreasing in SCR activity. |
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